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arXiv · 1609.07913

Stereochemical configuration and selective excitation of the chiral molecule halothane

Martin Pitzer·Gregor Kastirke·Phillip Burzynski·Miriam Weller·Daniel Metz·Jonathan Neff·Markus Waitz·Florian Trinter·Lothar Ph. H. Schmidt·Joshua B. Williams·Till Jahnke·Horst Schmidt-Böcking·Robert Berger·Reinhard Dörner·Markus Schöffler
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Abstract

X-ray single-photon ionization and fragmentation of the chiral molecule halothane (CHBrClCF${}_{3}$) from a racemic mixture have been investigated using the COLTRIMS (Cold Target Recoil Ion Momentum Spectroscopy) technique. Two important facets related to the core ionization of this species are examined: Firstly, the distinction of enantiomers (mirror isomers) and the determination of absolute configuration on a single-molecule level by four-body Coulomb explosion; secondly, the interplay of site-selective excitation and fragmentation patterns. These results are easily transferrable to other molecular species and show the wealth of features

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Martin Pitzer, Gregor Kastirke, Phillip Burzynski, Miriam Weller, Daniel Metz, Jonathan Neff, Markus Waitz, Florian Trinter, Lothar Ph. H. Schmidt, Joshua B. Williams, Till Jahnke, Horst Schmidt-Böcking, Robert Berger, Reinhard Dörner, Markus Schöffler. 2016-09-26. Stereochemical configuration and selective excitation of the chiral molecule halothane. https://doi.org/10.1088/0953-4075/49/23/234001

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