Shapes and singularities in triatic liquid crystal vesicles

Abstract

Determining the equilibrium configuration and shape of curved two-dimensional films with (generalized) liquid crystalline (LC) order is a difficult infinite dimensional problem of direct relevance to the study of generalized polymersomes, soft matter and the fascinating problem of understanding the origin and formation of shape (morphogenesis). The symmetry of the free energy of the LC film being considered and the topology of the surface to be determined often requires that the equilibrium configuration possesses singular structures in the form of topological defects such as disclinations for nematic films. The precise number and type of defect plays a fundamental role in restricting the space of possible equilibrium shapes. Flexible closed vesicles with spherical topology and nematic or smectic order, for example, inevitably possess four elementary strength $+1/2$ disclination defects positioned at the four vertices of a tetrahedral shell. Here we address the problem of determining the equilibrium shape of flexible vesicles with generalized LC order. The order parameter in these cases is an element of $S^1/Z_p$, for any positive integer $p$. We will focus on the case $p =3$, known as triatic LCs. We construct the appropriate order parameter for triatics and find the associated free energy. We then describe the structure of the elementary defects of strength $+1/3$ in flat space. Finally, we prove that sufficiently floppy triatic vesicles with the topology of the 2-sphere equilibrate to octahedral shells with strength $+1/3$ defects at each of the six vertices, independently of scale.