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arXiv · 1612.07502

Shannon entropy analysis of the stretched exponential process : application to various shear induced multilamellar vesicles system

Hirokazu Maruoka·Akio Nishimura·Makoto Yoshida·Keisuke Hatada
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Abstract

The stretched exponential function, $\exp[-(t/\tau_{K})^{\beta}]$, describes various relaxation processes while it has been suggested that the power exponent, $\beta$ is derived from the non-uniformity of the process. In this paper, we attempted to estimate this non-uniformity by introducing Shannon entropy. Shannon entropy evaluates the average information contents of the distribution function, which reflects statistical homogeneity. We investigated the relaxation process of shear induced multilamellar system, which is described with the stretched exponential function. Three types of shear (constant, square, sine) at different frequencies are attempted in order to determine their effects on the relaxation process. We found that the Shannon entropy to which the first moment was introduced is maximized at $\beta~=~1$ : a single exponential. The Shannon entropy of sine shear experiments exhibited the frequency dependence. Thus it is interpreted that the increase of the intensity of shearing and the thermodynamic entropy are reflected on the Shannon entropy. We discussed the meaning of the maximum Shannon entropy in terms of various points of view, it was found that it corresponds to the diffusion process free from the restriction such as geometrical constraints. The constraints and the non-uniformity of process were successfully estimated by Shannon entropy. This study gives a new insight of entropy in general.

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Hirokazu Maruoka, Akio Nishimura, Makoto Yoshida, Keisuke Hatada. 2016-12-22. Shannon entropy analysis of the stretched exponential process : application to various shear induced multilamellar vesicles system. https://doi.org/10.1016/j.chemphys.2018.08.020

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