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arXiv · 1703.04033

Electron Emission Area Depends on Electric Field and Unveils Field Emission Properties in Nanodiamond Films

Oksana Chubenko·Stanislav S. Baturin·Kiran Kumar Kovi·Anirudha V. Sumant·Sergey V. Baryshev
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Abstract

In this paper we study the effect of actual, locally resolved, field emission (FE) area on electron emission characteristics of uniform semimetallic nitrogen-incorporated ultrananocrystalline diamond ((N)UNCD) field emitters. To obtain the actual FE area, imaging experiments were carried out in a vacuum system in a parallel-plate configuration with a specialty anode phosphor screen. Electron emission micrographs were taken concurrently with $I$-$V$ characteristics measurements. It was found that in uniform (N)UNCD films the field emitting site distribution is not uniform across the surface, and that the actual FE area depends on the applied electric field. To quantify the actual FE area dependence on the applied electric field, a novel automated image processing algorithm was developed. The algorithm processes extensive imaging datasets and calculates emission area per image. By doing so, it was determined that the emitting area was always significantly smaller than the FE cathode surface area of 0.152 cm$^2$ available. Namely, the actual FE area would change from $5\times10^{-3}$ \% to 1.5 \% of the total cathode area with the applied electric field increased. Finally and most importantly, it was shown that when $I$-$E$ curves as measured in the experiment were normalized by the field-dependent emission area, the resulting $j$-$E$ curves demonstrated a strong kink and significant deviation from Fowler-Nordheim (FN) law, and eventually saturated at a current density of $\sim$100 mA/cm$^2$. This value was nearly identical for all studied (N)UNCD films, regardless of the substrate.

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Oksana Chubenko, Stanislav S. Baturin, Kiran Kumar Kovi, Anirudha V. Sumant, Sergey V. Baryshev. 2017-03-11. Electron Emission Area Depends on Electric Field and Unveils Field Emission Properties in Nanodiamond Films. https://doi.org/10.1021/acsami.7b07062

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