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arXiv · 1703.05582

Tracking Thermal-Induced Amorphization of a Zeolitic Imidazolate Framework via Synchrotron In Situ Far-Infrared Spectroscopy

Matthew R. Ryder·Thomas D. Bennett·Chris S. Kelley·Mark D. Frogley·Gianfelice Cinque·Jin-Chong Tan
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Abstract

We present the first use of in situ far-infrared spectroscopy to analyze the thermal amorphization of a zeolitic imidazolate framework material. We explain the nature of vibrational motion changes during the amorphization process and reveal new insights into the effect that temperature has on the Zn-N tetrahedra.

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Matthew R. Ryder, Thomas D. Bennett, Chris S. Kelley, Mark D. Frogley, Gianfelice Cinque, Jin-Chong Tan. 2017-03-16. Tracking Thermal-Induced Amorphization of a Zeolitic Imidazolate Framework via Synchrotron In Situ Far-Infrared Spectroscopy. https://arxiv.org/abs/1703.05582

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