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arXiv · 1703.06827

Detecting Molecular Rotational Dynamics Complementing the Low-Frequency Terahertz Vibrations in a Zirconium-Based Metal-Organic Framework

Matthew R. Ryder·Ben Van de Voorde·Bartolomeo Civalleri·Thomas D. Bennett·Sanghamitra Mukhopadhyay·Gianfelice Cinque·Felix Fernandez-Alonso·Dirk De Vos·Svemir Rudić·Jin-Chong Tan
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Abstract

We show clear experimental evidence of co-operative terahertz (THz) dynamics observed below 3 THz (~100 cm-1), for a low-symmetry Zr-based metal-organic framework (MOF) structure, termed MIL-140A [ZrO(O2C-C6H4-CO2)]. Utilizing a combination of high-resolution inelastic neutron scattering and synchrotron radiation far-infrared spectroscopy, we measured low-energy vibrations originating from the hindered rotations of organic linkers, whose energy barriers and detailed dynamics have been elucidated via ab initio density functional theory (DFT) calculations. For completeness, we obtained Raman spectra and characterized the alterations to the complex pore architecture caused by the THz rotations. We discovered an array of soft modes with trampoline-like motions, which could potentially be the source of anomalous mechanical phenomena, such as negative linear compressibility and negative thermal expansion. Our results also demonstrate coordinated shear dynamics (~2.5 THz), a mechanism which we have shown to destabilize MOF crystals, in the exact crystallographic direction of the minimum shear modulus (Gmin).

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Matthew R. Ryder, Ben Van de Voorde, Bartolomeo Civalleri, Thomas D. Bennett, Sanghamitra Mukhopadhyay, Gianfelice Cinque, Felix Fernandez-Alonso, Dirk De Vos, Svemir Rudić, Jin-Chong Tan. 2017-03-20. Detecting Molecular Rotational Dynamics Complementing the Low-Frequency Terahertz Vibrations in a Zirconium-Based Metal-Organic Framework. https://doi.org/10.1103/physrevlett.118.255502

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