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arXiv · 1703.08719

Reexamination of Tolman's law and the Gibbs adsorption equation for curved interfaces

Martin Thomas Horsch·Stefan Becker·Michaela Heier·Jayant Kumar Singh·Felix Diewald·Ralf Müller·George Jackson·Jadran Vrabec·Hans Hasse
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Abstract

In manuscript arXiv:1703.08719 [cond-mat.soft], it was claimed that the well-known deduction of Tolman's law is not rigorous, since Tolman's argument implies that two different definitions of the surface tension, called $\gamma$ and $\bar\gamma$ in the manuscript, coincide. This claim is retracted as it can be shown by free-energy minimization that $\gamma = \bar\gamma$ indeed holds for the Laplace radius. Joachim Gro\ss, Philipp Rehner, Carlos Vega, \O{}ivind Wilhelmsen, and the anonymous reviewers of The Journal of Chemical Physics contributed to finding the mistake in the manuscript.

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Martin Thomas Horsch, Stefan Becker, Michaela Heier, Jayant Kumar Singh, Felix Diewald, Ralf Müller, George Jackson, Jadran Vrabec, Hans Hasse. 2017-03-25. Reexamination of Tolman's law and the Gibbs adsorption equation for curved interfaces. https://arxiv.org/abs/1703.08719

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