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arXiv · 1705.03225

Time-dependent analysis of the mixed-field orientation of molecules without rotational symmetry

Linda V. Thesing·Jochen Küpper·Rosario González-Férez
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Abstract

We present a theoretical study of the mixed-field orientation of molecules without rotational symmetry. The time-dependent one-dimensional and three-dimensional orientation of a thermal ensemble of 6-chloropyridazine-3-carbonitrile molecules in combined linearly or elliptically polarized laser fields and tilted dc electric fields is computed. The results are in good agreement with recent experimental results of one-dimensional orientation for weak dc electric fields [J. Chem. Phys. 139, 234313 (2013)]. Moreover, they predict that using elliptically polarized laser fields or strong dc fields three-dimensional orientation is obtained. The field-dressed dynamics of excited rotational states is characterized by highly non-adiabatic effects. We analyze the sources of these non-adiabatic effects and investigate their impact on the mixed-field orientation for different field configurations in mixed-field-orientation experiments.

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Linda V. Thesing, Jochen Küpper, Rosario González-Férez. 2017-05-09. Time-dependent analysis of the mixed-field orientation of molecules without rotational symmetry. https://doi.org/10.1063/1.4986954

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