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arXiv · 1705.11137

Lattice and spin dynamics in a low-symmetry antiferromagnet NiWO$_4$

M. A. Prosnikov·V. Yu. Davydov·A. N. Smirnov·M. P. Volkov·R. V. Pisarev·P. Becker·L. Bohatý
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Abstract

Lattice and magnetic dynamics of NiWO$_4$ single crystals were studied with the use of polarized Raman spectroscopy in a wide temperature range of 10-300 K including the antiferromagnetic ordering temperature $T_N$=62 K. Static magnetic measurements were used for characterizing the single crystals. All Raman-active phonons predicted by the group theory were observed and characterized. Magnetic symmetry analysis was used to determine possible magnetic space groups for NiWO$_4$ which can be also applied to any other isostructural crystal with the same magnetic propagation vector k=(1/2,0,0). Though the magnetic structure of NiWO$_4$ is relatively simple, a rich set of narrow and broad magnetic excitations with different polarization properties and temperature behavior in the very broad frequency range of 10-200 cm$^{-1}$ was observed, with some modes surviving at temperatures much higher than $T_N$ up to 220 K. Part of the magnetic excitations was identified as acoustic and optical spin-wave branches which allow us to construct exchange structure and estimate exchange and anisotropy constants with the use of linear spin-wave theory. Since the magnetic structure can be described as exchange-coupled AFM chains of $S=1$ ions, previously unobserved magnetic excitation at 24 cm$^{-1}$ is tentatively assigned to a Haldane gap mode.

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M. A. Prosnikov, V. Yu. Davydov, A. N. Smirnov, M. P. Volkov, R. V. Pisarev, P. Becker, L. Bohatý. 2017-05-31. Lattice and spin dynamics in a low-symmetry antiferromagnet NiWO$_4$. https://doi.org/10.1103/physrevb.96.014428

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