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arXiv · 1709.04091

A theory for the effect of patch / non-patch attractions on the self-assembly of patchy colloids

Abstract

In this paper, we develop a thermodynamic perturbation theory to describe the self-assembly of patchy colloids which exhibit both patch-patch attractions as well as patch / non-patch attractions. That is, patches attract other patches as well as the no patch region. In general these attractions operate on different energy scales, which allows for controlled self-assembly as well as anomalous phase behavior. As an application we apply the model to the study of liquid water.

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Bennett D. Marshall. 2017-09-13. A theory for the effect of patch / non-patch attractions on the self-assembly of patchy colloids. https://doi.org/10.1039/c7sm01263b

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