The hydrogen atom according to wave mechanics in cartesian coordinates

J. F. Ogilvie

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arXiv · 1709.04759

The hydrogen atom according to wave mechanics in cartesian coordinates

J. F. Ogilvie

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Abstract

A partial separation of the variables is practicable for the solution of Schroedinger's temporally independent equation in cartesian coordinates x,y,z, which yields moderately simple algebraic formulae for the amplitude functions involving quantum numbers k,l,m, the same as in spherical polar coordinates. The properties of angular momentum are thus achieved with no angular variable. Several plots of surfaces of constant psi(x,y,z) are presented to illustrate the resemblance of the shapes of these surfaces to the shapes of surfaces of psi(r,theta,phi) with the corresponding quantum numbers.

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J. F. Ogilvie. 2017-08-30. The hydrogen atom according to wave mechanics in cartesian coordinates. https://arxiv.org/abs/1709.04759

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