arXiv · 1709.06939
Fabrication of porous microrings via laser printing and ion-beam post-etching
Abstract
Pulsed-laser dry printing of noble-metal microrings with a tunable internal porous structure, which can be revealed via an ion-beam etching post-procedure, was demonstrated. Abundance and average size of the pores inside the microrings were shown to be tuned in a wide range by varying incident pulse energy and a nitrogen doping level controlled in the process of magnetron deposition of the gold film in the appropriate gaseous environment. The fabricated porous microrings were shown to provide many-fold near-field enhancement of incident electromagnetic fields, which was confirmed by mapping of the characteristic Raman band of a nanometer-thick covering layer of Rhodamine 6G dye molecules and supporting finite-difference time-domain calculations. The proposed laser printing/ion-beam etching approach is demonstrated to be a unique tool aimed at designing and fabricating multifunctional plasmonic structures and metasurfaces for spectroscopic bioidentification based on surface-enhanced infrared absorption, Raman scattering and photoluminescence detection schemes.
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S. Syubaev, A. Nepomnyashchiy, E. Mitsai, E. Pustovalov, O. Vitrik, S. Kudryashov, A. Kuchmizhak. 2017-07-26. Fabrication of porous microrings via laser printing and ion-beam post-etching. https://doi.org/10.1063/1.4993885
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