Statistical Mechanics Basis of Macleod Formula

M. -E. Boudh-Hir; G. A. Mansoori

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arXiv · 1712.04508

Statistical Mechanics Basis of Macleod Formula

M. -E. Boudh-Hir·G. A. Mansoori

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Abstract

In this work the theoretical basis for the famous formula of Macleod, relating the surface tension of a liquid in equilibrium with its own vapor to the one-particle densities in the two phases of the system, is derived. Using the statistical- mechanical definition of the surface tension, it is proved that this property is, at the first approximation, given by the Macleod formula.

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M. -E. Boudh-Hir, G. A. Mansoori. 2017-12-06. Statistical Mechanics Basis of Macleod Formula. https://arxiv.org/abs/1712.04508

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