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arXiv · 1712.10220

Tuning a sign of magnetoelectric coupling in paramagnetic NH2(CH3)2Al1-xCrx(SO4)*6H2O crystals by metal ion substitution

V. Kapustianyk·Yu. Eliyashevskyy·Z. Czapla·V. Rudyk·R. Serkiz·N. Ostapenko·I. Hirnyk·J. -F. Dayen·M. Bobnar·R. Gumeniuk·B. Kundys
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Abstract

Hybrid organometallic systems offer a wide range of functionalities, including magnetoelectric interactions. However, the ability to design on-demand ME coupling remains challenging despite a variety of host-guest configurations and ME phases coexistence possibilities. Here, we report the effect of metal-ion substitution on the magnetic and electric properties in the paramagnetic ferroelectric DMAAS crystals. Doing so we are able to induce and even tune a sign of the ME interactions in the paramagnetic ferroelectric state. Both studied samples with 6.5% and 20% of Cr become paramagnetic, contrary to the initial diamagnetic compound. Due to the isomorphous substitution with Cr the ferroelectric phase transition temperature increases nonlinearly, with the shift being larger for the sample with Cr content of 6.5%. A magnetic field applied along the polar c axis increases ferroelectricity for this sample and shifts Tc to higher values, while inverse effects are observed for sample containing 20% of Cr. The ME coupling coefficient of 1.7ns/m found for a crystal with 20% of Cr is among the highest reported up to now. The observed sign change of ME coupling coefficient with a small change in Cr content paves the way for ME coupling engineering.

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V. Kapustianyk, Yu. Eliyashevskyy, Z. Czapla, V. Rudyk, R. Serkiz, N. Ostapenko, I. Hirnyk, J. -F. Dayen, M. Bobnar, R. Gumeniuk, B. Kundys. 2017-12-29. Tuning a sign of magnetoelectric coupling in paramagnetic NH2(CH3)2Al1-xCrx(SO4)*6H2O crystals by metal ion substitution. https://doi.org/10.1038/s41598-017-14388-8

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