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arXiv · 1802.08681

Polariton Chemistry: controlling molecular dynamics with optical cavities

Raphael F. Ribeiro·Luis A. Martínez-Martínez·Matthew Du·Jorge Campos-Gonzalez-Angulo·Joel Yuen-Zhou
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Abstract

Molecular polaritons are the optical excitations which emerge when molecular transitions interact strongly with confined electromagnetic fields. Increasing interest in the hybrid molecular-photonic materials that host these excitations stems from recent observations of their novel and tunable chemistry. Some of the remarkable functionalities exhibited by polaritons include the ability to induce long-range excitation energy transfer, enhance charge conductivity, and inhibit or enhance chemical reactions. In this review, we explain the effective theories of molecular polaritons which form a basis for the interpretation and guidance of experiments at the strong coupling limit. The theoretical discussion is illustrated with the analysis of innovative applications of strongly coupled molecular-photonic systems to chemical phenomena of fundamental importance to future technologies.

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Raphael F. Ribeiro, Luis A. Martínez-Martínez, Matthew Du, Jorge Campos-Gonzalez-Angulo, Joel Yuen-Zhou. 2018-02-23. Polariton Chemistry: controlling molecular dynamics with optical cavities. https://arxiv.org/abs/1802.08681

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