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arXiv · 1804.06704

On the Balance of Intercalation and Conversion Reactions in Battery Cathodes

Daniel C. Hannah·Gopalakrishnan Sai Gautam·Pieremanuele Canepa·Gerbrand Ceder
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Abstract

We present a thermodynamic analysis of the driving forces for intercalation and conversion reactions in battery cathodes across a range of possible working ion, transition metal, and anion chemistries. Using this body of results, we analyze the importance of polymorph selection as well as chemical composition on the ability of a host cathode to support intercalation reactions. We find that the accessibility of high energy charged polymorphs in oxides generally leads to larger intercalation voltages favoring intercalation reactions, whereas sulfides and selenides tend to favor conversion reactions. Furthermore, we observe that Cr-containing cathodes favor intercalation more strongly than those with other transition metals. Finally, we conclude that two-electron reduction of transition metals (as is possible with the intercalation of a $2+$ ion) will favor conversion reactions in the compositions we studied.

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Daniel C. Hannah, Gopalakrishnan Sai Gautam, Pieremanuele Canepa, Gerbrand Ceder. 2018-04-18. On the Balance of Intercalation and Conversion Reactions in Battery Cathodes. https://doi.org/10.1002/aenm.201800379

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