Theory of Confined High Tc Superconductivity in Monovalent Metals

Ganapathy Baskaran

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arXiv · 1808.02005

Theory of Confined High Tc Superconductivity in Monovalent Metals

Ganapathy Baskaran

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Abstract

Monovalent non-transition metals are robust Fermi liquids. They defy superconductivity even at lowest temperatures (Li is a minor exception:Tc $\approx$ 0.4 mK). However, Thapa and Pandey \cite{ThapaPandey} have recently reported signals for ambient temperature granular superconductivity in Ag nanoparticle embedded in Au matrix. We develop a theory, where competing superconducing, CDW and SDW orders lose and get confined (go off-shell). They leave behind a robust Fermi liquid on-shell. \textit{A single half filled band crossing the Fermi level} provides a number of special k-space regions for \textit{singlet stabilizing umklapp pair scattering and superconductivity stabilizing repulsive pair scattering}. Carefully designed perturbations could deconfine a confined superconductivity. We suggest that electron transfer (doping) from Ag nanoparticles to Au matrix (with a higher electronegativity), quasi 2d structural reconstructions (e.g., 9R structure) at Ag-Au interfaces etc., bring out confined superconductivity. Beneath a calm Fermi sea, strong supercurrents may exist in several metals.

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Ganapathy Baskaran. 2018-08-06. Theory of Confined High Tc Superconductivity in Monovalent Metals. https://arxiv.org/abs/1808.02005

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