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arXiv · 1809.07397

Electron paramagnetic resonance enhanced crystal field analysis for low point-group symmetry systems: C$_{2v}$ sites in Sm$^{3+}$:CaF$_2$/SrF$_2$

Sebastian P Horvath·Jon-Paul R Wells·Michael F Reid·Mitsuo Yamaga·Makoto Honda
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Abstract

We present a comprehensive spectroscopic study of C$_{2v}$ point-group symmetry sites in Sm$^{3+}$:CaF$_2$/SrF$_2$ codoped with either NaF or LiF. Data includes electron paramagnetic resonance measurements of Zeeman and hyperfine interactions for the ground state, as well as site-selective excitation and fluorescence spectroscopy up to the $^{4}$G$_{5/2}$ multiplet. Inclusion of the EPR data allowed us to determine unique crystal-field parameters. The parameters provide information about the geometry of the sites and the nature of the interactions between the Sm$^{3+}$ dopant and the alkaline earth co-dopant.

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Sebastian P Horvath, Jon-Paul R Wells, Michael F Reid, Mitsuo Yamaga, Makoto Honda. 2018-09-19. Electron paramagnetic resonance enhanced crystal field analysis for low point-group symmetry systems: C$_{2v}$ sites in Sm$^{3+}$:CaF$_2$/SrF$_2$. https://doi.org/10.1088/1361-648x/aaee5c

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