Implicit temporal discretization and exact energy conservation for particle methods applied to the Poisson-Boltzmann equation

Abstract

Wereportonanewmultiscalemethodapproachforthestudyofsystemswith wide separation of short-range forces acting on short time scales and long-range forces acting on much slower scales. We consider the case of the Poisson-Boltzmann equation that describes the long-range forces using the Boltzmann formula (i.e. we assume the medium to be in quasi local thermal equilibrium). We developed a new approach where fields and particle information (mediated by the equations for their moments) are solved self-consistently. The new approach is implicit and numerically stable, providing exact energy conservation. We tested different implementations all leading to exact energy conservation. The new method requires the solution of a large set of non-linear equations. We considered three solution strategies: Jacobian Free Newton Krylov, an alternative, called field hiding, based on hiding part of the residual calculation and replacing them with direct solutions and a Direct Newton Schwarz solver that considers simplified single particle-based Jacobian. The field hiding strategy proves to be the most efficient approach.