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arXiv · 1811.00158

Transferability of crystal-field parameters for rare-earth ions in Y$_2$SiO$_5$ tested by Zeeman spectroscopy

Nicholas L. Jobbitt·Simon J. Patchett·Yashar Alizadeh·Michael F. Reid·Jon-Paul R. Wells·Sebastian P. Horvath·Jevon J. Longdell·Alban Ferrier·Philippe Goldner
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Abstract

Zeeman spectroscopy is used to demonstrate that phenomenological crystal-field parameters determined for the two $C_1$ point-group sites in Er$^{3+}$:Y$_2$SiO$_5$ may be transferred to other ions. The two crystallographic six- and seven-coordinate substitutional sites may be distinguished by comparing the spectra with crystal-field calculations.

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Nicholas L. Jobbitt, Simon J. Patchett, Yashar Alizadeh, Michael F. Reid, Jon-Paul R. Wells, Sebastian P. Horvath, Jevon J. Longdell, Alban Ferrier, Philippe Goldner. 2018-10-31. Transferability of crystal-field parameters for rare-earth ions in Y$_2$SiO$_5$ tested by Zeeman spectroscopy. https://doi.org/10.1134/s1063783419050123

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