Carbon Monoxide Adsorption and Carbon Monoxide Oxidation Studies on Thiolate Supported Gold Nanoclusters Dispensed on Metallic Oxides

Dilek Demir

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arXiv · 1811.01999

Carbon Monoxide Adsorption and Carbon Monoxide Oxidation Studies on Thiolate Supported Gold Nanoclusters Dispensed on Metallic Oxides

Dilek Demir

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Abstract

Thiolate-protected gold nanoclusters represent atomically well-defined active centers for catalysis with resolved crystal structures, enabling the creation of a homogeneous and defined surface. The correlation of characterization via FT-IR spectroscopy with kinetics studies gives insight into the gold clusters activity and tests their utilization to bridge the gap between organometallic complex-based homogenous catalysis and nanoparticle based heterogeneous catalysis as well as the gap between the bulk crystal structure model catalysis and real-world catalysis.

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Dilek Demir. 2018-10-08. Carbon Monoxide Adsorption and Carbon Monoxide Oxidation Studies on Thiolate Supported Gold Nanoclusters Dispensed on Metallic Oxides. https://arxiv.org/abs/1811.01999

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