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arXiv · 1811.09983

Quantum crystals are at odds with the laws of thermodynamics

François Fillaux
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Abstract

Experimental data and the principles of quantum mechanics suggest that a crystal is a condensate of `wavicles' enclosed in a box, where `wavicle' denotes the indefinite wave-particle status of the microscopic constituents. When it is not perturbed the crystal is in a classical-like state. The wavefunction, the internal energy and the entropy are all of them equal to zero. The thermodynamic temperature is indefinite. Perturbations via energy- and/or momentum-transfer reveal quantum effects. The temperature laws for the heat capacities of some hydrogen-bonded crystals are rationalized with superposition states depending on the quantum temperature which is crystal-dependent. Heat-transfer is a coherent anentropic process. Apart from energy conservation, the other laws of thermodynamics are irrelevant.

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François Fillaux. 2018-11-25. Quantum crystals are at odds with the laws of thermodynamics. https://arxiv.org/abs/1811.09983

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