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arXiv · 1903.01825

Cluster expansions with renormalized activities and applications to colloids

Sabine Jansen·Dimitrios Tsagkarogiannis
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Abstract

We consider a binary system of small and large objects in the continuous space interacting via a non-negative potential. By integrating over the small objects, the effective interaction between the large ones becomes multi-body. We prove convergence of the cluster expansion for the grand canonical ensemble of the effective system of large objects. To perform the combinatorial estimate of hypergraphs (due to the multi-body origin of the interaction) we exploit the underlying structure of the original binary system. Moreover, we obtain a sufficient condition for convergence which involves the surface of the large objects rather than their volume. This amounts to a significant improvement in comparison to a direct application of the known cluster expansion theorems. Our result is valid for the particular case of hard spheres (colloids) for which we rigorously treat the depletion interaction.

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Sabine Jansen, Dimitrios Tsagkarogiannis. 2019-03-05. Cluster expansions with renormalized activities and applications to colloids. https://doi.org/10.1007/s00023-019-00868-2

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