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arXiv · 1903.05458

On the duality of ring and ladder diagrams and its importance for many-electron perturbation theories

Andreas Irmler·Felix Hummel·Andreas Grüneis
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Abstract

We present a diagrammatic decomposition of the transition pair correlation function for the uniform electron gas. We demonstrate explicitly that ring and ladder diagrams are dual counterparts that capture significant long- and short-ranged interelectronic correlation effects, respectively. Our findings help to guide the further development of approximate many-electron theories and reveal that the contribution of the ladder diagrams to the electronic correlation energy can be approximated in an effective manner using second-order perturbation theory. We employ the latter approximation to reduce the computational cost of coupled cluster theory calculations for insulators and semiconductors by two orders of magnitude without compromising accuracy.

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Andreas Irmler, Felix Hummel, Andreas Grüneis. 2019-03-13. On the duality of ring and ladder diagrams and its importance for many-electron perturbation theories. https://doi.org/10.1103/physrevlett.123.156401

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