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arXiv · 1903.11120

Comment on "Chiral Phase Transition in Charge Ordered 1T-TiSe2" and Supplementary Material on "First-order Forbidden X-ray Diffraction"

Meng-Kai Lin·Joseph A. Hlevyack·Peng Chen·Ro-Ya Liu·T. -C. Chiang
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Abstract

A prior report of the emergence of chirality for the (2x2x2) charge density wave (CDW) in TiSe2 has attracted much interest; the drastic symmetry breaking is highly unusual with few precedents [1]. In that study, key evidence was provided by x-ray diffraction measurements of two superlattice reflections, (1.5 1.5 0.5) and (2.5 1 0). The (2.5 1 0) reflection appeared to show an anomalously large intensity and a transition onset at ~7 K below that of the (1.5 1.5 0.5) reflection. These observations, aided by modeling, were cited as evidence for a separate chiral transition. In this Comment, we show that the prior conclusions based on x-ray diffraction are erroneous. There is just one transition, and it is achiral.

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Meng-Kai Lin, Joseph A. Hlevyack, Peng Chen, Ro-Ya Liu, T. -C. Chiang. 2019-03-26. Comment on "Chiral Phase Transition in Charge Ordered 1T-TiSe2" and Supplementary Material on "First-order Forbidden X-ray Diffraction". https://doi.org/10.1103/physrevlett.122.229701

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