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arXiv · 1904.08143

Aqueous metal-organic solutions for YSZ thin film inkjet deposition

C. Gadea·Q. Hanniet·A. Lesch·D. Marani·S. H. Jensen·V. Esposito
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Abstract

Inkjet printing of 8% Y2O3-stabilized ZrO2 (YSZ) thin films is achieved by designing a novel water-based reactive ink for Drop-on-Demand (DoD) inkjet printing. The ink formulation is based on a novel chemical strategy that consists of a combination of metal oxide precursors (zirconium alkoxide and yttrium salt), water and a nucleophilic agent, i.e. n-methyldiethanolamine (MDEA). This chemistry leads to metal-organic complexes with long term ink stability and high precision printability. Ink rheology and chemical reactivity are analyzed and controlled in terms of metal-organic interactions in the solutions. Thin dense nanocrystalline YSZ film below 150 nm are obtained by low temperature calcination treatments (400-500 {\deg}C), making the deposition suitable for a large variety of substrates, including silicon, glass and metals. Thin films and printed patterns achieve full densification with no lateral shrinkage and high ionic conductivity.

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C. Gadea, Q. Hanniet, A. Lesch, D. Marani, S. H. Jensen, V. Esposito. 2019-04-17. Aqueous metal-organic solutions for YSZ thin film inkjet deposition. https://doi.org/10.1039/c7tc01879g

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