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arXiv · 1906.05385

Quantification model of X-ray fluorescence analysis based on iterative Monte Carlo procedure

I. Szaloki·A. Gerenyi·G. Radocz
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Abstract

Iterative Monte Carlo algorithm has been constructed and tested for quantification of X-ray fluorescence analysis in order to determine the atomic composition of solid materials. The calculation model uses simulation code MCNP6 that describes the excitation and relaxation phenomenon in the atomic electron shell. The complete analytical procedure was tested by quantitative analysis of standard reference alloy materials. Acceptable agreement was found between the calculated and nominal concentrations within the standard deviations of the concentrations of the major elements. The total duration of the repeatedly performed Monte Carlo numerical computation for the entire analysis was only a few minutes, due to the application of variance reduction procedures available in the Monte Carlo code. A frame software was designed and written in MatLab programming environment for controlling the iterative calculation of the elementary composition of the sample material.

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I. Szaloki, A. Gerenyi, G. Radocz. 2019-06-11. Quantification model of X-ray fluorescence analysis based on iterative Monte Carlo procedure. https://arxiv.org/abs/1906.05385

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