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arXiv · 1912.03198

Modelization of charge carriers mobilities in halide perovskites: Fröhlich scattering and quantum localization effects in a dynamic disorder regime

Antoine Lacroix·Guy Trambly de Laissardière·Pascal Quémerais·Jean-Pierre Julien·Didier Mayou
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Abstract

We analyze the quantum transport properties of MAPbI3 within a tight-binding model. Charge carriers are strongly scattered by the Fröhlich interaction with longitudinal optical phonon modes. This limits their mobilities at room temperature to the order of 200 cm$^2$/Vs. In the presence of additional extrinsic disorder the mobility decreases and a large fraction of the electronic states at band edges can be localized. These states would be insulating if the lattice were static, but their localization is broken by the dynamic disorder induced by the vibrations of the longitudinal optical modes. This process of electrons and holes diffusion, driven by the lattice dynamics, contributes to the unique electronic properties of this material.

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Antoine Lacroix, Guy Trambly de Laissardière, Pascal Quémerais, Jean-Pierre Julien, Didier Mayou. 2019-12-20. Modelization of charge carriers mobilities in halide perovskites: Fröhlich scattering and quantum localization effects in a dynamic disorder regime. https://doi.org/10.1103/physrevlett.124.196601

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