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arXiv · 1912.11137

Asymptotic Behavior of a Sequence of Conditional Probability Distributions and the Canonical Ensemble

Yu-Chen Cheng·Hong Qian·Yizhe Zhu
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Abstract

The probability distribution of a function of a subsystem conditioned on the value of the function of the whole, in the limit when the ratio of their values goes to zero, has a limit law: It equals the unconditioned marginal probability distribution weighted by an exponential factor whose exponent is uniquely determined by the condition. We apply this theorem to explain the canonical equilibrium ensemble of a system in contact with a heat reservoir. Since the theorem only requires analysis at the level of the function of the subsystem and reservoir, it is applicable even without the knowledge of the composition of the reservoir itself, which extends the applicability of the canonical ensemble. Furthermore, we generalize our theorem to a model with strong interaction that contributes an additional term to the exponent, which is beyond the typical case of approximately additive functions. This result is new in both physics and mathematics, as a theory for the Gibbs conditioning principle for strongly correlated systems. A corollary provides a precise formulation of what a temperature bath is in probabilistic term

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Yu-Chen Cheng, Hong Qian, Yizhe Zhu. 2019-12-23. Asymptotic Behavior of a Sequence of Conditional Probability Distributions and the Canonical Ensemble. https://doi.org/10.1007/s00023-020-01011-2

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