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arXiv · 2004.04121

Thermal transport enhancement of hybrid nanocomposites; impact of confined water inside nanoporous silicon

Mykola Isaiev·Xiaorui Wang·Konstantinos Termentzidis·David Lacroix
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Abstract

The thermal transport properties of porous silicon and nano-hybrid "porous silicon/water" systems are presented here. The thermal conductivity was evaluated with equilibrium molecular dynamics technique for porous systems made of spherical voids or water-filled cavities. We revealed large thermal conductivity enhancement in the nano-hybrid systems as compared to their dry porous counterparts, which cannot be captured by effective media theory. This rise of thermal conductivity is related to the increases of the specific surface of the liquid/solid interface. We demonstrated that significant difference for more than two folds of thermal conductivity of pristine porous silicon and "porous silicon liquid/composite" is due to the liquid density fluctuation close to "solid/liquid interface" (layering effect). This effect is getting more important for the high specific surface of the interfacial area. Specifically, the enhancement of the effective thermal conductivity is 50 % for specific surface area of 0.3 (1/nm), and it increases further upon the increase of the surface to volume ratio. Our study provides valuable insights into the thermal properties of hybrid liquid/solid nanocomposites and about the importance of confined liquids within nanoporous materials.

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Mykola Isaiev, Xiaorui Wang, Konstantinos Termentzidis, David Lacroix. 2020-04-08. Thermal transport enhancement of hybrid nanocomposites; impact of confined water inside nanoporous silicon. https://doi.org/10.1063/5.0014680

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