arXiv · 2004.07082
Correlating chemical composition and optical properties of photochromic rare-earth oxy-hydrides using ion beam analysis
Abstract
We relate the photochromic response of rare-earth oxy-hydride thin films (YHO, NdHO, GdHO and DyHO) synthesized by reactive magnetron sputtering to chemical composition. Depth profiles of the sample composition are extracted by a multi-method ion beam analysis approach. The total areal density of the thin films is deduced from Rutherford Backscattering Spectrometry while coincidence Time-of-Flight/Energy Elastic Recoil Detection Analysis provides depth-profiles of the film constituents. High-resolution depth profiles of the concentration of light species, i.e. hydrogen and oxygen, are additionally extracted from Nuclear Reaction Analysis and Elastic Backscattering Spectrometry, respectively. The photochromic response of the films is measured by optical transmission spectroscopy before and after illumination. We report photochromic properties for YHO, NdHO, GdHO and DyHO for chemical compositions described by the formula $REH_{2-\delta}O_{\delta}$ in the range of $0.45 {<} {\delta} {<} 1.5$.
Explore related subjects
Keep this discovery
S. M. Aðalsteinsson, M. V. Moro, D. Moldarev, S. Droulias, M. Wolff, D. Primetzhofer. 2020-04-15. Correlating chemical composition and optical properties of photochromic rare-earth oxy-hydrides using ion beam analysis. https://doi.org/10.1016/j.nimb.2020.09.016
Cite the original work for its findings. Save a collection to share your selection of sources.