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arXiv · 2005.01647

Compatibility of $Zr_{2}AlC$ MAX phase-based ceramics with oxygen-poor, static liquid lead-bismuth eutectic

Bensu Tunca·Thomas Lapauw·Carolien Callaert·Joke Hadermann·Remi Delville·El'ad N. Caspi·Martin Dahlqvist·Johanna Rosén·Amalraj Marshal·Konda G. Pradeep·Jochen M. Schneider·Jozef Vleugels·Konstantina Lambrinou
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Abstract

This work investigates the compatibility of $Zr_{2}AlC$ MAX phase-based ceramics with liquid LBE, and proposes a mechanism to explain the observed local $Zr_{2}AlC$/LBE interaction. The ceramics were exposed to oxygen-poor ($C_{O}\le2.2 \cdot10^{-10}$ mass%), static liquid LBE at 500{\deg}C for 1000 h. A new $Zr_{2}(Al,Bi,Pb)C$ MAX phase solid solution formed in-situ in the LBE-affected $Zr_{2}AlC$ grains. Out-of-plane ordering was favorable in the new solid solution, whereby $\textit{A}$-layers with high and low-Bi/Pb contents alternated in the crystal structure, in agreement with first-principles calculations. Bulk $Zr_{2}(Al,Bi,Pb)C$ was synthesized by reactive hot pressing to study the crystal structure of the solid solution by neutron diffraction.

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Bensu Tunca, Thomas Lapauw, Carolien Callaert, Joke Hadermann, Remi Delville, El'ad N. Caspi, Martin Dahlqvist, Johanna Rosén, Amalraj Marshal, Konda G. Pradeep, Jochen M. Schneider, Jozef Vleugels, Konstantina Lambrinou. 2020-05-04. Compatibility of $Zr_{2}AlC$ MAX phase-based ceramics with oxygen-poor, static liquid lead-bismuth eutectic. https://doi.org/10.1016/j.corsci.2020.108704

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