Ion specificity modulated inhomogeneous interfacial flow inhibits bubble coalescence in electrolyte solutions

Abstract

Inhibition of bubble coalescence in electrolyte solutions enables the formation of oceanic whitecaps and affects the heat and mass transfer in many bubble related engineering processes. For different electrolytes, the ability to inhibit bubble coalescence correlates to the ion specificity at the air water interface at an abnormal cation-anion pair relationship, rather than the typically expected cation or anion series that was widely reported in atmospheric, bio- and chemical processes. Here we show that the inhomogeneous interfacial flow, at a different electrolyte concentration from the solution because of the surface specificity of both cation and anion, contributes to the bubble coalescence inhibition behavior in electrolyte solutions. The interfacial flow, achieved with the mobile air-water interface, contributes to the continuous change of electrolyte concentration within the liquid film formed between two colliding bubbles, thereby resulting in a concentration gradient of electrolytes between the thin film and the bulk solution. The electrolyte concentration gradient, hence surface tension gradient, becomes significant to resist film thinning when the film thickness reaches tens of nanometers. The retarded film thinning between two bubbles and delayed bubble coalescence were experimentally captured by high-speed interferometry and quantitatively explained by the proposed electrolyte transportation model. This finding clearly highlights the coupled effect of interfacial flow and ion specificity, and shows important implications for improved understanding of ocean waves, for future development of colloidal science in high concentration electrolyte solutions that is critical for biology, and benefits many applied fields like water splitting and mineral extraction.