Sound velocities of Lennard-Jones systems near the liquid-solid phase transition

Sergey Khrapak

doi:10.3390/molecules25153498

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arXiv · 2008.00858

Sound velocities of Lennard-Jones systems near the liquid-solid phase transition

Sergey Khrapak

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Abstract

Longitudinal and transverse sound velocities of Lennard-Jones systems are calculated at the liquid-solid coexistence using the additivity principle. The results are shown to agree well with the ``exact'' values obtained from their relations to excess energy and pressure. Some consequences, in particular, in the context of the Lindemann's melting rule and Stokes-Einstein relation between the self-diffusion and viscosity coefficients are discussed. Comparison with available experimental data on the sound velocities of solid argon at melting conditions is provided.

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Sergey Khrapak. 2020-08-03. Sound velocities of Lennard-Jones systems near the liquid-solid phase transition. https://doi.org/10.3390/molecules25153498

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