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arXiv · 2011.14942

Tough sheets of nanowires produced floating in the gas phase

Richard S. Schäufele·Miguel Vazquez-Pufleau·Juan J. Vilatela
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Abstract

Assembling nanostructured building blocks into network materials unlocks macroscopic properties inaccessible with monolithic solids, notably toughness and tolerance to electrochemical alloying. A method is reported for large-scale, continuous synthesis of silicon nanowires (SiNWs) suspended in the gas phase and their direct assembly into macroscopic sheets. Performing gas-phase growth of SiNWs through floating catalyst chemical vapor deposition using an aerosol of gold nanoparticles eliminates the need for substrates, increasing the growth rate by a factor of 500, reaching 1.4 $\mu$m s$^{-1}$ and leading to very long SiNWs. The combined high aspect ratio ($>$210) and large concentration of SiNWs in the gas-phase (1.5 x 107 cm$^{-3}$) enable the formation of macroscopic solids solely composed of percolated SiNWs, such as free-standing sheets and continuous metre-long SiNW tapes. Sheet samples of small diameter SiNWs ($<$25 nm) combine extraordinary flexibility in bending, tensile ductility around 3%, and over 50-fold higher toughness than Si-based anodes (fracture energy 0.18 $\pm$ 0.1 J g$^{-1}$). This synthesis and assembly process should be applicable to virtually any one-dimensional inorganic nanomaterial producible by thermochemical methods.

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Richard S. Schäufele, Miguel Vazquez-Pufleau, Juan J. Vilatela. 2020-11-30. Tough sheets of nanowires produced floating in the gas phase. https://doi.org/10.1039/d0mh00777c

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