Prediction of phonon-mediated superconductivity with high critical temperature in the two-dimensional topological semimetal W2N3

Abstract

Two-dimensional superconductors attract great interest both for their fundamental physics and for their potential applications, especially in the rapidly growing field of quantum computing. Despite intense theoretical and experimental efforts, materials with a reasonably high transition temperature are still rare. Even more rare are those that combine superconductivity with a non-trivial band topology, to potentially host exotic states of matter such as Majorana fermions. Here, we predict a remarkably high superconducting critical temperature of 21-28 K in the easily exfoliable, topologically non-trivial 2D semimetal W2N3 . By studying its electronic and superconducting properties as a function of doping and strain, we find large changes in the electron-phonon interactions that make this material a unique platform to study different coupling regimes and test the limits of current theories of superconductivity. Last, we discuss the possibility of tuning the material to achieve coexistence of superconductivity and topologically non-trivial edge states.