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arXiv · 2103.03909

Reservoirs, Fick law and the Darken effect

Anna De Masi·Immacolata Merola·Errico Presutti
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Abstract

We study the stationary measures of Ginzburg-Landau (GL) stochastic processes which describe the magnetization flux induced by the interaction with reservoirs. To privilege simplicity to generality we restrict to quadratic Hamiltonians where almost explicit formulas can be derived. We discuss the case where reservoirs are represented by boundary generators (mathematical reservoirs) and compare with more physical reservoirs made by large-infinite systems. We prove the validity of the Fick law away from the boundaries. %and the existence of boundary layers for the mathematical reservoirs. We also obtain in the context of the GL models a mathematical proof of the Darken effect which shows uphill diffusion of carbon in specimen partly doped with the addition of Si.

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Anna De Masi, Immacolata Merola, Errico Presutti. 2021-03-05. Reservoirs, Fick law and the Darken effect. https://doi.org/10.1063/5.0049680

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