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arXiv · 2104.02418

In-situ dispersion of electrospun nanofibers in PDMS for fabrication of high strength, transparent nanocomposites

Shital Rokade·Prasoon Kumar
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Abstract

The polymer nanocomposites find applications in diverse areas ranging from smart materials to bioengineering. They are developed by dispersion of nanomaterials in a bulk phase of a polymeric material. Although several methods facilitate efficient dispersion of nanomaterials in a bulk polymer matrix to create nanocomposites, majority of them follows heat, beat and treat processes. These processes are high energy demanding processes. Moreover, the challenge increases when nanomaterials need to be dispersed in a viscous polymeric material. This results in spatial heterogeneity in the dispersion of nanomaterials, eventually leading to compromised mechanical properties of a nanocomposite. Therefore, in the current work, we propose an in-situ, on-step fabrication process of polydimethylsiloxane (PDMS) nanocomposites. Electrospun polyvinyl alcohol (PVA) nanofibers are homogenously dispersed in a PDMS matrix to create a high strength, transparent PDMS nanocomposite. The homogenous dispersion of nanofibers in PDMS matrix is characterised by scanning electron microscopy (SEM), confocal imaging and rheological studies. Further, the prepared PDMS nanocomposite exhibits improved mechanical strength and comparable optical transparency in comparison to native PDMS. Hence, the fabricated PDMS nanocomposites, being resistant to mechanical stress and optically transparent, will find applications as transdermal patches, flexible electronics, microfluidic devices and others.

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Shital Rokade, Prasoon Kumar. 2021-04-06. In-situ dispersion of electrospun nanofibers in PDMS for fabrication of high strength, transparent nanocomposites. https://arxiv.org/abs/2104.02418

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