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arXiv · 2104.03033

Point Defects in Crystals of Charged Colloids

Rinske M. Alkemade·Marjolein de Jager·Berend van der Meer·Frank Smallenburg·Laura Filion
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Abstract

Charged colloidal particles - both on the nano and micron scales - have been instrumental in enhancing our understanding of both atomic and colloidal crystals. These systems can be straightforwardly realized in the lab, and tuned to self-assemble into body-centered cubic (BCC) and face-centered cubic (FCC) crystals. While these crystals will always exhibit a finite number of point defects, including vacancies and interstitials - which can dramatically impact their material properties - their existence is usually ignored in scientific studies. Here, we use computer simulations and free-energy calculations to characterize vacancies and interstitials in both FCC and BCC crystals of point-Yukawa particles. We show that, in the BCC phase, defects are surprisingly more common than in the FCC phase, and the interstitials manifest as so-called crowdions: an exotic one-dimensional defect proposed to exist in atomic BCC crystals. Our results open the door to directly observing these elusive defects in the lab.

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Rinske M. Alkemade, Marjolein de Jager, Berend van der Meer, Frank Smallenburg, Laura Filion. 2021-04-07. Point Defects in Crystals of Charged Colloids. https://doi.org/10.1063/5.0047034

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