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arXiv · 2105.04199

Robust magnetic anisotropy of a monolayer of hexacoordinate Fe( ii ) complexes assembled on Cu(111)

Massine Kelai·Benjamin Cahier·Mihail Atanasov·Frank Neese·Yongfeng Tong·Luqiong Zhang·Amandine Bellec·Olga Iasco·Eric Rivière·Régis Guillot·Cyril Chacon·Yann Girard·Jérôme Lagoute·Sylvie Rousset·Vincent Repain·Edwige Otero·Marie-Anne Arrio·Philippe Sainctavit·Anne-Laure Barra·Marie-Laure Boillot·Talal Mallah
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Abstract

The tris pyrazolyl borate ligand imposes a rigid scaffold around Fe( ii ) ensuring a robust magnetic anisotropy when the molecules assembled as monolayers suffer from the dissymmetric environment of the substrate/vacuum interface.

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Massine Kelai, Benjamin Cahier, Mihail Atanasov, Frank Neese, Yongfeng Tong, Luqiong Zhang, Amandine Bellec, Olga Iasco, Eric Rivière, Régis Guillot, Cyril Chacon, Yann Girard, Jérôme Lagoute, Sylvie Rousset, Vincent Repain, Edwige Otero, Marie-Anne Arrio, Philippe Sainctavit, Anne-Laure Barra, Marie-Laure Boillot, Talal Mallah. 2021-05-10. Robust magnetic anisotropy of a monolayer of hexacoordinate Fe( ii ) complexes assembled on Cu(111). https://doi.org/10.1039/d1qi00085c

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