Excluded volume effects in polymer brushes at moderate chain stretching

Dirk Romeis; Michael Lang

doi:10.1063/1.4894503

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arXiv · 2105.11835

Excluded volume effects in polymer brushes at moderate chain stretching

Dirk Romeis·Michael Lang

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Abstract

We develop a strong stretching approximation for a polymer brush made of self-avoiding polymer chains. The density profile of the brush and the distribution of the end monomer positions in stretching direction are computed and compared with simulation data. We find that our approach leads to a clearly better approximation as compared to previous approaches based upon Gaussian elasticity at low grafting densities (moderate chain stretching), for which corrections due to finite extensibility can be ignored.

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Dirk Romeis, Michael Lang. 2021-05-25. Excluded volume effects in polymer brushes at moderate chain stretching. https://doi.org/10.1063/1.4894503

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