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arXiv · 2107.09915

Influence of Shape Resonances on the Angular Dependence of Molecular Photoionization Delays

Fabian Holzmeier·Jennifer Joseph·Jean-Christophe Houver·Mogens Lebech·Danielle Dowek·Robert R. Lucchese
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Abstract

Characterizing time delays in molecular photoionization as a function of the ejected electron emission direction relative to the orientation of the molecule and the light polarization axis pro-vides unprecedented insights into the attosecond dynamics induced by extreme ultraviolet or X-ray one-photon absorption, including the role of electronic correlation and continuum resonant states. Here, we report completely resolved experimental and computational angular depend-ence of single-photon ionization delays in NO molecules across a shape resonance, relying on synchrotron radiation and time independent ab initio calculations. The angle-dependent time delay variations of few hundreds of attoseconds, resulting from the interference of the resonant and non-resonant contributions to the dynamics of the ejected electron, are well described using a multichannel Fano model where the resonance time delay is angle-independent. Comparing these results with the same resonance computed in e-NO+ scattering highlights the connection of photoionization delays with Wigner scattering time delays.

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Fabian Holzmeier, Jennifer Joseph, Jean-Christophe Houver, Mogens Lebech, Danielle Dowek, Robert R. Lucchese. 2021-07-21. Influence of Shape Resonances on the Angular Dependence of Molecular Photoionization Delays. https://doi.org/10.1038/s41467-021-27360-y

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