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arXiv · 2108.11447

Magnetic properties of BiFeO$_3$-BaTiO$_3$ ceramics in the morphotropic phase boundary: a role of crystal structure and structural parameters

D. V. Karpinsky·M. V. Silibin·D. V. Zhaludkevich·S. I. Latushka·A. V. Sysa·V. V. Sikolenko·A. L. Zhaludkevich·V. A. Khomchenko·A. Franz·K. Mazeika·D. Baltrunas·A. Kareiva
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Abstract

A correlation between the crystal structure and magnetic properties of system (1-x)BiFeO$_3$-(x)BaTiO$_3$ with compounds across the morphotropic phase boundary was studied using X-ray and neutron diffraction, magnetometry, and Mossbauer spectroscopy measurements. Increase in the dopants content leads to the structural transition from the rhombohedral phase to the cubic phase via a formation of the two-phase region (0.2 < x < 0.33), wherein the magnetic structure changes from the modulated G-type antiferromagnetic to the collinear antiferromagnetic via a stabilization of the non-collinear antiferromagnetic phase with non-zero remanent magnetization. The value of magnetic moment calculated per iron ion based on the Mossbauer and neutron diffraction data decreases from m = 4.4 mB for the compound with x=0.25 to m=3.2 mB for the compound with x=0.35 testifying a dominance of 3+ oxidation state of the iron ions. Increase in the amount of the cubic phase leads to a reduction in the remanent magnetization from 0.02 emu.g for the compounds with the dominant rhombohedral phase (x < 0.27) down to about 0.001 emu/g for the compounds with dominant cubic structure (x >= 0.27). Rapid decrease in the remanent magnetization observed in the compounds across the phase coexistence region points at no direct correlation between the type of structural distortion and non-zero remanent magnetization, while the oxygen octahedra tilting is the key factor determining the presence of non-zero remanent magnetization.

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D. V. Karpinsky, M. V. Silibin, D. V. Zhaludkevich, S. I. Latushka, A. V. Sysa, V. V. Sikolenko, A. L. Zhaludkevich, V. A. Khomchenko, A. Franz, K. Mazeika, D. Baltrunas, A. Kareiva. 2021-08-25. Magnetic properties of BiFeO$_3$-BaTiO$_3$ ceramics in the morphotropic phase boundary: a role of crystal structure and structural parameters. https://doi.org/10.1016/j.jmmm.2021.168409

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