Searcharxiv⌕ Search
Home/Archive/arXiv

arXiv · 2111.03681

Surface plasmons on a Au waveguide electrode open new redox channels associated with the transfer of energetic carriers

Zohreh Hirbodvash·Oleksiy Krupin·Howard Northfield·Anthony Olivieri·Elena A. Baranova·Pierre Berini
View original source ↗Read source document ↗Export metadata ↓

Abstract

Plasmonic catalysis holds significant promise for opening new reaction pathways inaccessible thermally, or for improving the efficiency of chemical processes. However, challenges persist in distinguishing photothermal effects from effects due to energetic electrons and/or holes excited in the metal comprising a plasmonic structure. Here we use a Au stripe waveguide along which surface plasmon polaritons (SPPs) propagate, operating simultaneously as a working electrode in a 3-electrode electrochemical cell. Cyclic voltammograms were obtained under SPP excitation as a function of incident optical power and wavelength ~ 1350 nm, enabling processes involving energetic holes to be separated from processes involving energetic electrons by investigating oxidation and reduction reactions separately. Redox current densities increase by 10x under SPP excitation. The oxidation, reduction and equilibrium potentials drop by as much as 2x and split beyond a clear threshold with SPP power in correlation with the photon energy. The temperature of the working electrode under SPP excitation is monitored in situ and independent control experiments isolate thermal effects. Chronoamperometry measurements with on-off modulated SPPs at 600 Hz, yield a diffusion-limited rapid current response modulated at the same frequency, ruling out thermally-enhanced mass transport. Our observations are attributed to the opening of optically controlled non-equilibrium redox channels associated with energetic carrier transfer to the redox species.

Explore related subjects

physics.opticsphysics.chem-ph

Keep this discovery

BibTeXRIS

Zohreh Hirbodvash, Oleksiy Krupin, Howard Northfield, Anthony Olivieri, Elena A. Baranova, Pierre Berini. 2021-11-05. Surface plasmons on a Au waveguide electrode open new redox channels associated with the transfer of energetic carriers. https://arxiv.org/abs/2111.03681

Cite the original work for its findings. Save a collection to share your selection of sources.

KEEP EXPLORING

Related papers

arXiv2026

Two-step high-accuracy microwave frequency measurement and time-frequency analysis based on optical frequency combs

Broadband microwave frequency measurement and time-frequency analysis are crucial for applications such as electronic warfare. However, when it comes to ultra wideband signal analysis, traditional electronic methods have high analysis accuracy, but intrinsic electronic bottlenecks limit their real-time analysis. Here, we propose and experimentally demonstrate a two-step microwave frequency measurement and time-frequency analysis method based on optical frequency combs. The system first performs coarse frequency localization over the 0-40 GHz range using stimulated-Brillouin-scattering-assisted frequency-to-time mapping (FTTM) and dual-comb channelized reception. The dual-comb is then reapplied for downconverting the signal under test, followed by digital signal processing to achieve high-accuracy unambiguous frequency extraction. Experimental results show that the system achieves mean single-tone frequency measurement errors of less than 10 kHz over 0-40 GHz. We further experimentally measure multi-tone, linearly frequency-modulated, and V-shaped frequency-modulated signals, demonstrating the proposed method's capability for analyzing complex signals.

physics.optics↗
arXiv2026

A Two-Mirror Faceted Projection System for EUV Lithography

We propose an all-reflective two-mirror projection system for extreme ultraviolet (EUV) lithography operating at exposure wavelengths of $13.5$~nm (Mo/Si) and $11.2$~nm (Ru/Be), delivering a fourfold ($4\times$) demagnification of the periodic mask pattern at a numerical aperture approaching unity ($\mathrm{NA}_{\max} \approx 0.993$). In contrast to conventional EUV projection objectives that incorporate 6--10 aspheric mirrors with an overall optical throughput of less than $15\%$, the proposed design redirects each accepted discrete spatial diffraction order scattered by the mask onto the wafer via a dedicated pair of planar mirror facets. The number of reflections is strictly fixed at two for all accepted orders, retaining $50$--$60\%$ of the power leaving the mask in each accepted order. We derive a spatial geometry providing rigorous optical path length equalization across all diffraction orders, thereby removing order-dependent propagation phase shifts. Individually optimized 30-bilayer Bragg multilayer coatings are designed for each facet using the transfer matrix method combined with global evolutionary optimization algorithms. The architecture is generalized to a three-dimensional vector formulation with a two-dimensionally periodic mask. Utilizing inverse lithography technology, Fourier parameterization, and a differentiable electromagnetic modal waveguide solver, we solve the synthesis problem for binary absorber masks (La absorber on a Ru/Be/Sr multilayer mirror). We demonstrate simulated aerial images of sub-10-nm features on the wafer (isolated peaks with a full width at half maximum (FWHM) of approximately $5.4$~nm and line pairs with a critical dimension of $6$~nm) and find that the two peaks remain resolved for the tested wafer defocus values from $0$ to $5$~nm along the $z$-axis.

physics.optics↗
arXiv2026

Antimony for broadband nanophotonics across the ultraviolet, visible and infrared

Semimetal elemental antimony (Sb) nanostructures show great potential for applications where nanophotonic properties play a key role, such as phase-change optical memories, non-linear optical elements, photothermal therapy agents, photodetectors and photocatalysts. However, designing advanced Sb-based photonic devices critically requires an accurate and reliable knowledge of the optical response of bulk and nanoscale Sb. Herein, we report for the first time a fully consistent and accurately measured dielectric function for Sb nanoscale films in a wide spectral range from the ultraviolet to the far infrared (4 - 0.04 eV, i.e. ~ 0.3 - 30 $\mu$m), surpassing previous reports that explored a limited spectral range. It is found that the Sb spectral response is driven exclusively by giant interband transitions in the visible up to mid infrared (4 - 0.4 eV, i.e. ~ 0.3 - 3 $\mu$m), and that their contribution dominates over that of free carriers down to 0.12 eV (i.e. ~ 10 $\mu$m). Such spectral response enables Sb nanostructures to display spectrally selective and tunable nanophotonic resonances. First, we showcase interband plasmonic resonances in the visible-to-near infrared for Sb nanogratings. Second, we report giant refractive index dielectric resonances in the mid infrared for nanostructured Sb/dielectric/metal resonant cavities. These findings open a pathway to optimized planar Sb nanoscale designs enabling a tailored light-matter interaction, which will be useful for integrated data, telecom, medical, optoelectronic and energy conversion devices operating in a broad spectral range.

physics.optics↗