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arXiv · 2112.14982

Phase evolution and enhanced room temperature piezoelectric properties response of lead-free Ru doped BaTiO3 ceramic

Kumar Brajesh·Sudhir Ranjan·Ashish Garg
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Abstract

Recent years have witnessed considerable work on the development of lead-free piezoelectric ceramic materials and their structure-property correlations. The development of piezo response is a strong function of phase evolution in these materials. In this work, we report the effect of Ru doping and consequent phase evolution on maximization of piezoelectric response of polycrystalline lead-free barium titanate, depicted as Ba(RuxTi1-x)O3 (BRT). The samples were prepared in a narrow compositional range of using conventional solid-state reaction method. Ru doping increases the leakage current of BaTiO3 samples attributed to increased oxygen vacancy concentration due to substitution of Ti4+ by Ru3+. Detailed structural analysis reveals samples exhibiting coexistence of tetragonal (space group: P4mm) and orthorhombic (space group: Amm2) structured phases near the room temperature reveal relatively enhanced piezoelectric properties. The BRT sample with Ru content of 2 mol% yields a maximum longitudinal piezoelectric coefficient, d33 of 269 pC/N, a high strain value of 0.16% with a large remnant polarization of 19 micro C/cm2 and a coercive field of 5.8 kV/cm. We propose that the 4d orbital of Ruthenium plays a crucial role in improving the functional properties and in decreasing the ferroelectric Curie temperature (Tc). Our work provides clues into tailoring the phase evolution for designing lead-free piezoelectric materials with enhanced piezoelectric property.

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Kumar Brajesh, Sudhir Ranjan, Ashish Garg. 2021-12-30. Phase evolution and enhanced room temperature piezoelectric properties response of lead-free Ru doped BaTiO3 ceramic. https://arxiv.org/abs/2112.14982

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