Searcharxiv⌕ Search
Home/Archive/arXiv

arXiv · 2201.09552

Formation of Zn and Pb sulfides in a redox-sensitive modern system due to high atmospheric fallout

Beata Smieja-Król·Mirosława Pawlyta·Mariola Kądziołka-Gaweł·Barbara Fiałkiewicz-Kozieł
View original source ↗Read source document ↗Export metadata ↓

Abstract

The study shows that the air-derived metal enrichment (up to 2.3 g Zn kg-1, 1.1 g Pb kg-1, and 62 mg Cd kg-1) is retained in a thin layer (~30 cm) around 10-15 cm below the peat surface. A combination of focused ion beam (FIB) technology and scanning (SEM) and transmission (TEM) electron microscopy reveals that micrometric spheroids are most characteristic for ZnS and (Zn,Cd)S, although the sulfides readily form pseudomorphs after different plant tissues resulting in much larger aggregates. The aggregates have a complex polycrystalline sphalerite structure much more advanced than typically obtained during low-temperature synthesis or observed in other modern occurrences. Platy highly-disordered radially-aggregated submicrometre crystals develop within the time constraints of several decades in the cold (~15{\deg}C) and acid (pH 3.4-4.4) peat. The less abundant Pb sulfides occur as submicron cube-like crystals between ZnS or as flat irregular or square patches on plant root macrofossils. All PbS are crystalline and defect-free. Pb ion complexation with dissolved and solid organic matter is probably responsible for the low number and equilibrium shape of PbS crystals. Iron is absent in the authigenic sulfide mineralization and occurs entirely as organically bound ferric iron (Fe3+), as revealed by Mossbauer spectroscopy. The different affinity of metals to organic matter enhances the precipitation of Zn and Cd as sulfides over Pb and Fe. Our findings demonstrate that human activities lead to the formation of near-surface stratiform metal sulfide accumulations in peat, and the polluted sites can be of use to understand and reconstruct ancient ore deposits' genesis and mechanisms of formation.

Explore related subjects

cond-mat.mtrl-sci

Keep this discovery

BibTeXRIS

Beata Smieja-Król, Mirosława Pawlyta, Mariola Kądziołka-Gaweł, Barbara Fiałkiewicz-Kozieł. 2022-01-24. Formation of Zn and Pb sulfides in a redox-sensitive modern system due to high atmospheric fallout. https://doi.org/10.1016/j.gca.2021.11.032

Cite the original work for its findings. Save a collection to share your selection of sources.

KEEP EXPLORING

Related papers

arXiv2026

Measuring chiral phonons

Chiral phonons are quantized vibrations where the atomic motion in a solid breaks improper rotation symmetries. In many cases, chiral phonons possess angular momenta and are therefore selective to circularly polarized light. Both fundamental and applied research efforts on chiral phonons have been gaining increasing attention owing to their importance in a variety of fields including spintronics, spin-selective chemical reactions, thermal transport, quantum information processing and biosensing, where the bi-directional spin-lattice coupling enabled by chiral phonons can be harnessed in new ways, and potentially lead to new functionalities. Thus far, the studies of chiral phonons across diverse materials platforms have evolved largely independently within these fields, but the experimental techniques are often interrelated. In this perspective, we present a detailed description, as well as advantages and disadvantages of the current approaches for experimentally measuring chiral phonons in chiral and achiral materials. We conclude with a discussion of new methods for measuring chiral phonons. Ultimately, this work seeks to offer an experimental guide for systematically investigating the properties of chiral phonons in various materials systems and applications.

cond-mat.mtrl-sci↗
arXiv2026

A model of grain growth in UN integrating molecular dynamics, phase-field modeling, and uncertainty quantification

Grain growth kinetics and grain-boundary (GB) properties in uranium mononitride (UN) are investigated through an integrated multiscale framework combining molecular dynamics (MD), phase-field modeling, and surrogate-assisted uncertainty quantification. MD simulations yield GB energies for 27 symmetric tilt boundaries from 0--2000~K, which are consistent with available DFT values. The average GB energy is nearly temperature-independent below 1000~K and increases at higher temperatures. A mechanistic pore-drag model applied to the only available grain growth dataset for actinide nitrides yields a mobility reduction factor of $s \approx 0.93$--$0.99$, statistically indistinguishable from unity, confirming that pore drag is negligible under the experimental conditions. The intrinsic GB mobility is therefore extracted directly from the effective mobility, yielding $M_0 = 2.05\times10^{-15}$~m$^4$/(J$\cdot$s) and $Q_M = 0.89$~eV. Phase-field simulations conducted from 1500--2000~K confirm normal curvature-driven grain growth, with grain size distributions converging to the Hillert-like form. A surrogate-assisted global sensitivity analysis---combining principal component analysis, Gaussian process regression, and Sobol decomposition---reveals that the mobility prefactor $M_0$ dominates output variance at all times, followed by the activation energy $Q_M$, while the GB energy $\gamma$ contributes minimally. These results establish the first quantitative grain growth framework for UN and identify the reduction of uncertainty in $M_0$ and $Q_M$ as the highest-priority target for future experimental efforts.

cond-mat.mtrl-sci↗
arXiv2026

Silicon Solar Cell Design for >30% Efficiency via Singlet Fission

Singlet fission (SF) materials convert high-energy photons into multiple charge carriers, providing a route to exceed the efficiency limits of single-junction silicon solar cells without many of the complexities of multi-junction tandem designs. Following the first demonstration of an SF-enhanced silicon solar cell in 2025, there is a need to understand how SF materials can be effectively integrated into high-efficiency industrial silicon devices and translated from proof of concept to a manufacturable technology. Using coupled optical and electrical simulations, we assess the efficiency potential of several industrially relevant silicon cell architectures combined with SF materials. Interdigitated back-contact (IBC) cells offer the greatest potential for improvement due to unrestricted front-surface access and can achieve efficiencies exceeding 33%. However, performance is highly sensitive to front-surface passivation quality. Appropriate silicon design, particularly controlled surface doping and fixed interfacial charge, can mitigate recombination losses and relax passivation requirements for ultra-thin exciton-transfer layers.

cond-mat.mtrl-sci↗