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arXiv · 2201.09937

On the crystallization Kinetics in Natural Rubber

Rabia Laghmach·Nicolas Candau·Laurent Chazeau·Thierry Biben
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Abstract

In this article, we introduce a framework to investigate the growth of nano-crystallites in a polymer matrix numerically. This framework combines the Flory theory of entropic elasticity with phase-field approaches commonly used to model crystal growth. We investigate in particular the growth kinetics of a crystallite in the presence of topological constraints such as entanglements or cross-links, and show that depending on the coupling between the topological constraints and the growth kinetics various structures can be observed: branched structures looking like spherulites or stable nano-crystallites as observed in strain-induced crystallization.

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Rabia Laghmach, Nicolas Candau, Laurent Chazeau, Thierry Biben. 2022-01-24. On the crystallization Kinetics in Natural Rubber. https://arxiv.org/abs/2201.09937

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