From sub-aging to hyper-aging in structural glasses

Abstract

We demonstrate non-equilibrium scaling laws for the aging dynamics in glass formers that emerge from combining a recent application of Onsager's theory of irreversible processes with the equilibrium scaling laws of glassy dynamics. Different scaling regimes are predicted for the evolution of the system's structural relaxation time $τ$ with age (waiting time $t_w$), depending on the depth of the quench from the liquid into the glass: \emph{simple aging} ($τ\sim t_w$) applies for quenches close to the critical point of mode-coupling theory (MCT) and implies \emph{sub-aging} ($τ\approx\ t_w^δ$ with $δ<1$) as a broad cross-over for quenches to nearly-arrested equilibrium states; \emph{hyper-aging} (or \emph{super-aging}, $τ\sim t_w^{δ'}$ with $δ'>1$) emerges for quenches deep into the glass. The latter is cut off by non-mean-field fluctuations that we account for within a recent extension of MCT, the stochastic $β$-relaxation theory (SBR). We exemplify the scaling laws by a schematic model that allows to quantitatively fit recent simulation results for density-quenched hard-sphere-like particles.