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arXiv · 2203.15478

Multielectron effect in the strong-field ionization of aligned nonpolar molecules

M. Abu-samha·Lars Bojer Madsen
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Abstract

We revisit strong-field ionization of aligned O$_2$, CO$_2$, and CS$_2$ molecules in light of recent advances in the field of strong-field physics, in particular the inclusion of multielectron polarization in the numerical solution of the time-dependent Schr{\"o}dinger equation (TDSE) within the singe-active-electron approximation. Upon inclusion of multielectron polarization and the associated induced dipole potential in the TDSE model, we obtain angular distributions of total ionization yields which are in better agreement with the available experimental results for CO$_2$ and CS$_2$. For the probed molecules, the main effect of the multielectron polarization on the photoelectron momentum distributions (PMDs) is captured by the introduction of a field at short distances that counteracts the applied external field and leads to a vanishing time-dependent interaction within a certain cut-off radius. Hence, for the PMDs we find no imprints of the long-range part of the laser-induced dipole potential.

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M. Abu-samha, Lars Bojer Madsen. 2022-03-29. Multielectron effect in the strong-field ionization of aligned nonpolar molecules. https://doi.org/10.1103/physreva.106.013117

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