arXiv · 2205.11886
Analyzing the photoassociation spectra of ultracold $^{85}$Rb$^{133}$Cs molecule in $(3)^3\Sigma^+$ state
Abstract
We establish a theoretical model to analyze the photoassociative (PA) spectroscopy of $(3)^3\Sigma^+$ state of $^{85}$Rb$^{133}$Cs molecule. The term energy, spin-spin coupling constants and hyperfine interaction constant of nine vibrational levels in the $(3)^3\Sigma^+$ state are determined. Based on the fitted term energy and rotation constant, the potential energy curve of $(3)^3\Sigma^+$ state is obtained by using the RKR method which is compared with the ab initial potential curve.
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Zi-wei Wang, Zi-ang Li, Xu-hui Bai, Ting Gong, Zhong-hua Ji, Yan-ting Zhao, Gao-ren Wang. 2022-05-24. Analyzing the photoassociation spectra of ultracold $^{85}$Rb$^{133}$Cs molecule in $(3)^3\Sigma^+$ state. https://arxiv.org/abs/2205.11886
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